By Gwilherm Evano, Nicolas Blanchard
Providing accomplished perception into using copper in cross-coupling reactions, Copper-Mediated Cross-Coupling Reactions provides an entire updated choice of the to be had reactions and catalytic structures for the formation of carbon-heteroatom and carbon-carbon bonds. This crucial reference covers a vast scope of copper-mediated reactions, their diversifications, key advances, advancements, and an array of educational and commercial functions that experience revolutionized the sector of natural synthesis. The textual content additionally discusses the mechanism of those modifications, using copper as in your price range replacement to palladium, in addition to lately constructed tools for undertaking copper-mediated reactions with supported catalysts.
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Additional resources for Copper-Mediated Cross-Coupling Reactions
J. Org. Chem. 1999, 64, 670–674.  Chan, D. M. ; Monaco, K. ; Winter, M. P. Tetrahedron Lett. 1998, 39, 2933–2936.  Evans, D. ; Katz, J. ; West, T. R. Tetrahedron Lett. 1998, 39, 2937–2940.  Lam, P. Y. ; Clark, C. ; Winters, M. ; Chan, D. M. ; Combs, A. Tetrahedron Lett. 1998, 39, 2941–2944. CONTRIBUTORS Carole Alayrac, Laboratoire de Chimie Moléculaire et Thioorganique, UMR CNRS 6507, INC3M, FR3038, ENSICAEN & Université de Caen BasseNormandie, 6 boulevard du Maréchal Juin, 14050 Caen, France Irina P.
China xxxiii xxxiv Contributors Annie-Claude Gaumont, Laboratoire de Chimie Moléculaire et Thioorganique, UMR CNRS 6507, INC3M, FR3038, ENSICAEN & Université de Caen Basse-Normandie, 6 boulevard du Maréchal Juin, 14050 Caen, France Céline Guissart, Laboratoire de Chimie Organique, Service de Chimie et PhysicoChimie Organiques, Université Libre de Bruxelles, Avenue F. D. Roosevelt 50, CP160/06, B-1050 Brussels, Belgium Ruimao Hua, Department of Chemistry, Tsinghua University, Beijing 100084, P. R.
1) 5 examples 47–78% yield (Eq. 10 Copper-catalyzed cross coupling of aryl iodides and amines in 2-dimethylaminoethanol. copper source was found to have a marked influence in this coupling reaction because the combination of copper(I) iodide and rac-BINOL gave relatively low yields. 9, Eq. 1, Eq. 4). 10, Eq. 10, Eq. 2). [19c] Besides N,O and O,O-bidentate ligands, N,N-ligands have also been used for the development of efficient catalytic systems for the arylation of amines. 11 Copper-catalyzed cross coupling of aryl iodides with amino acids and amino alcohols in 2-dimethylaminoethanol and water.
Copper-Mediated Cross-Coupling Reactions by Gwilherm Evano, Nicolas Blanchard