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Consequently, the fluidity of such compounds in the liquid state is low: that is, their viscosity is high. Vaporization of compounds of this type does require a break-up of the network of bonds, and the vapour effectively consists of fragments of the solid. In the case of diamond, these are C2 molecules; for silica, they are SiO2 molecules. Silicon carbide decomposes. Note It is important to be able to work out the overall composition of a compound from diagrams of the kind given in the discussion above.
Com 41 On the nature of the limiting types of binary compound Introduction to Inorganic Chemistry (iv) A simple model of a metal, therefore, is that of a collection of metal ions, held together by the appropriate number of electrons situated between them, the electrons being readily made to move by supplying further electrons at one point of the metal and taking electrons away at another. In the solid, the electrons hold the ions together in a rigid assembly: in the liquid, the ions are free to move.
1 Ordinary valency The valency (V) of an atom may be defined as the number of hydrogen or fluorine atoms with which the atom will combine. The assumption is made that hydrogen and fluorine are always univalent. To obtain the number of hydrogen or fluorine atoms (X) with which an atom (A) will combine, one looks at compounds formed between A and X, and picks out the one in which there are no A−A bonds. If this is molecular it will have the formula AXn, if non-molecular (AXn)∞. The valency of A is then given by n.
Introduction To Inorganic Chemistry by Nelson